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Crystal structure of diethyl [(4-nitro-phenyl-amino)(2-hy-droxy-phen-yl)meth-yl]phospho-nate methanol monosolvate. | LitMetric

Crystal structure of diethyl [(4-nitro-phenyl-amino)(2-hy-droxy-phen-yl)meth-yl]phospho-nate methanol monosolvate.

Acta Crystallogr Sect E Struct Rep Online

Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China.

Published: September 2014

AI Article Synopsis

  • The compound C17H21N2O6P·CH3OH features a 4-nitro-aniline and a 2-hydroxy-phenyl group arranged at an angle of 84.04°.
  • The phosphorus atom has a tetrahedral shape, bonded to two O-ethyl groups, a carbon atom, and a double-bonded oxygen.
  • In the crystal structure, various hydrogen bonds connect the α-amino-phosphonic acid and methanol, forming chains aligned along the a axis.

Article Abstract

In the title compound, C17H21N2O6P·CH3OH, the planes of the 4-nitro-aniline and 2-hy-droxy-phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra-hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the α-amino-phospho-nic acid and methanol mol-ecules into chains that propagate parallel to the a axis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186192PMC
http://dx.doi.org/10.1107/S1600536814018649DOI Listing

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