High-quality Bi2 S3 nanowires are synthesized by chemical vapor deposition and their intrinsic photoresponsive and field-effect characteristics are explored in detail. Among the studied Au-Au, Ag-Ag, and Au-Ag electrode pairs, the device with stepwise band alignment of asymmetric Au-Ag electrodes has the highest mobility. Furthermore, it is shown that light can cause a sevenfold decrease of the on/off ratio. This can be explained by the photoexcited charge carriers that are more beneficial to the increase of Ioff than Ion . The photoresponsive properties of the asymmetric Au-Ag electrode devices were also explored, and the results show a photoconductive gain of seven with a rise time of 2.9 s and a decay time of 1.6 s.
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http://dx.doi.org/10.1002/cphc.201402594 | DOI Listing |
Bioelectrochemistry
December 2024
Molecular Electronics Laboratory, Department of Bioelectronics and Biosensors, Science Campus, Alagappa University, Karaikudi 630003, Tamil Nadu, India. Electronic address:
Traumatic brain injury (TBI) induces neurogenerative disorders affecting severely daily human activities and early diagnosis is a critical requirement for prevention and cure. Here, we induced TBI formation in the Zebra fish, a model organism, by both mechanical (ultrasonic cleaner generated convulsive shock, UGCS) and chemical (pentylenetetrazol, PTZ) methods. The TBI induced cellular and neuronal changes are monitored by measuring the activities of the indicator biomarkers viz.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
September 2024
Department of Electrical and Computer Engineering, Virginia Tech, Blacksburg, Virginia 24061, United States.
Electrokinetic surface-enhanced Raman spectroscopy (EK-SERS) is an emerging high-order analytical technique that combines the plasmonic sensitivity of SERS with the electrode interfacial molecular control of electrokinetics. However, previous EK-SERS works primarily focused on non-Faradaic direct current (DC) operation, limiting the understanding of the underlying mechanisms. Additionally, developing reliable EK-SERS devices with electrically connected plasmonic hotspots remains challenging for achieving high sensitivity and reproducibility in EK-SERS measurements.
View Article and Find Full Text PDFJ Phys Chem Lett
September 2024
Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012, India.
Nanostructuring can greatly improve the electrode stability of rechargeable battery systems, such as Zn-Ag. In this report, we investigate the physical mechanisms by which nanostructuring alters structural properties of nanomaterials and thereby influences the structural stability of electrodes. We specifically consider the effects of Au-based nanoscaffolds on Ag.
View Article and Find Full Text PDFMikrochim Acta
July 2024
Key Laboratory of Chemical Utilization of Plant Resources of Nanchang, Institute of Functional Materials and Agricultural Applied Chemistry, College of Chemistry and Material, Jiangxi Agricultural University, Nanchang, 330045, China.
The stability of black phosphorene (BP) and its preparation and modification for developing and applying devices have become a hot topic in the interdisciplinary field. We propose ultrasound-electrochemistry co-assisted liquid-phase exfoliation as an eco-friendly one-step method to prepare gold-silver bimetallic nanoparticles (Au-AgNPs)-decorated BP nanozyme for smartphone-based portable sensing of 4-nitrophenol (4-NP) in different water sources. The structure, morphology, composition, and properties of Au-AgNPs-BP nanozyme are characterized by multiple instrumental analyses.
View Article and Find Full Text PDFACS Catal
June 2024
Department of Materials Science and Chemical Physics & Institute of Theoretical and Computational Chemistry (IQTC), University of Barcelona, Barcelona 08028, Spain.
The electrode-electrolyte interface, and in particular the nature of the cation, has considerable effects on the activity and product selectivity of the electrochemical reduction of CO. Therefore, to improve the electrocatalysis of this challenging reaction, it is paramount to ascertain whether cation effects on adsorbed intermediates are systematic. Here, DFT calculations are used to show that the effects of K, Na, and Mg, on single carbon CO reduction intermediates can either be stabilizing or destabilizing depending on the metal and the adsorbate.
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