Ruthenium-catalyzed double-fold C-H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate.

Chem Commun (Camb)

School of Materials Science and Engineering, Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China.

Published: November 2014

An efficient ruthenium-catalyzed double-fold C-H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products.

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Source
http://dx.doi.org/10.1039/c4cc05173dDOI Listing

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