The aggregates of perylenediimide based chemosensor (PDI 1) undergo de-aggregation induced fluorescence quenching selectively with ClO4(-) ions both in the solution and in the solid phase and can detect ClO4(-) ions in drinking water and fireworks. PDI 1 is permeable to C6 glioma cells, and ClO4(-) can be detected using confocal microscopy.
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http://dx.doi.org/10.1039/c4cc06765g | DOI Listing |
Environ Technol
January 2025
Department of Chemistry, Sathyabama Institute of Science and Technology, Chennai, India.
Inorganic anions such as chloride (Cl), nitrate (), sulfate (), carbonate (), bicarbonate (), dihydrogen phosphate (), fluoride (F) are ubiquitous in water matrices, play a significant role in the degradation of organic pollutants by Fenton process. In the present study, the performance of Fenton process in the presence of these anions was studied using phenol as a model compound along with the underlying mechanism and their tolerance limit. The presence of these anions affects the rate constant of the Fenton process and decreases in the following order, ---Cl > > > > F.
View Article and Find Full Text PDFLuminescence
January 2025
Department of Chemistry, School of Advanced Engineering, UPES Dehradun, Dehradun, Uttarakhand, India.
Anions play a crucial role in various environmental, chemical, and biological processes. Among various anions, the production of perchlorate (ClO ) ion is expected to rise in upcoming years, and thus, an efficient method for the detection of perchlorate ion is highly desirable. In this effort, a pyridyl-benzimidazole-based luminescent probe (RSB1) containing two N-H donor sites has been synthesized for selective detection of perchlorate ion.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia.
Designing molecular receptors that bind anions in water is a significant challenge, and an even greater difficulty lies in using these receptors to remove anions from water without resorting to the hazardous liquid-liquid extraction approach. We here demonstrate an effective and synthetically simple strategy toward these goals by exploiting ion-pair assembly of macrocycles. Our anion binding ensemble consists of an octa-chloro tetra-urea macrocyclic anion receptor (ClTU), which forms water-dispersible aggregates, and a tetra-cationic fluorescent dye 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin (TMPyP4), which provides Coulombic stabilization and fluorescence reporting of anion binding in an ion-pair assembly.
View Article and Find Full Text PDFCurr Top Med Chem
January 2025
Laboratório de Estudos Avançados de Microrganismos Emergentes e Resistentes (LEAMER), Departamento de Microbiologia Geral, Instituto de Microbiologia Paulo de Góes (IMPG), Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, Brazil.
Background: Scedosporium apiospermum is a multidrug-resistant filamentous fungus that causes localized and disseminated diseases. Our group has previously described that metalbased complexes containing copper(II) or silver(I) ions complexed with 1,10-phenanthroline-5,6- dione (phendione) inhibited the viability of S. apiospermum conidial cells.
View Article and Find Full Text PDFPhotochem Photobiol Sci
December 2024
Ivanovo State University of Chemistry and Technology, Sheremetevskii Pr. 7, Ivanovo, 153000, Russia.
Colorimetric chemosensors L and L, based on isoniazid hydrazones, have been designed for the highly sensitive and selective recognition of CN ion. Competing experiments were conducted with various other anions such as F, Cl, Br, I, SCN, ClO, ClO, NO, HPO, SO, and HSO in an acetonitrile solution. In the UV-Vis spectra, a bathochromic shift in the absorption bands of both hydrazones was observed following the addition of cyanide.
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