Nano-composite containing zinc oxide-tin oxide was obtained by a facile co-precipitation route using tin chloride tetrahydrate and zinc chloride as precursors and coated on glass by Doctor Blade deposition. The crystalline structure and morphology of composites were evaluated by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The XRD results showed peaks relative to zinc oxide with hexagonal wurtzite structure and tin oxide with tetragonal structure. FESEM observations showed that the nano-composite consisted of aggregates of particles with an average particle size of 18 nm. The photocatalytic activity of the pure SnO2, pure ZnO, ZnSnO3-Zn2SnO4 and ZnO-SnO2 nano-structure thin films was examined using the degradation of a textile dye Reactive Blue 160 (KE2B). ZnO-SnO2 nano-composite showed enhanced photo-catalytic activity than the pure zinc oxide and tin oxide. The enhanced photo-catalytic activity of the nano-composite was ascribed to an improved charge separation of the photo-generated electron-hole pairs.
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http://dx.doi.org/10.1016/j.saa.2014.09.013 | DOI Listing |
J Photochem Photobiol B
December 2024
Department of Chemistry, KPR Institute of Engineering and Technology, Coimbatore, Tamilnadu 641 407, India.
Over the last decade, the environmental and wellness cost of antibiotic drug resistance to the societies have been astounding and require urgent attention Metal oxide nanomaterials have been achieved a pull-on deal with its entire applications in biological and photocatalytic applications. The present study conducts a comparative investigation on chemical and biogenic synthesis of zirconium dioxide (ZrO) nanoparticles aimed at enhancing their efficacy in their applications. The plant extract of Passiflora edulis act as a reducing and capping properties offering a sustainable and eco-friendly alternative.
View Article and Find Full Text PDFAppl Biochem Biotechnol
January 2025
Ethnopharmacology and Algal Biotechnology Laboratory, Department of Botany, School of Life Sciences, Periyar University, Salem, Tamil Nadu, 636011, India.
In this present investigation, plant-mediated synthesis of titanium oxide (TiO) nanoparticles was synthesized from seagrass (Thalassia hemprichi) using the hot plate combustion method (HPCM). Synthesized TiO nanoparticles optical, functional, structural, and morphology properties were analyzed by UV-visible spectroscopy, Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). SEM analysis confirmed the spherical shape of the TiO nanoparticles were observed in various sizes, viz.
View Article and Find Full Text PDFChemSusChem
January 2025
Korea Institute of Energy Technology, Energy Engineering, 21 KENTECH-gil, 58330, Naju-si, KOREA, REPUBLIC OF.
Cu2O has attracted significant attention as a potential photocatalyst for CO2 reduction. However, its practical use is limited by rapid charge recombination, insufficient catalytic sites, and poor stability. In this study, we report a facile synthesis of Cu2O@BiOCl core-shell hybrids with well-defined shape of Cu2O and two-dimensional nanosheet structure of BiOCl.
View Article and Find Full Text PDFDiscov Nano
January 2025
Department of Chemical Engineering, Military Technical College (MTC), Cairo, Egypt.
The world is now facing a water scarcity crisis due to waste, pollution, and uneven distribution of freshwater resources, which are limited. Thus, the creation of innovative, economical, and effective methods for purifying water is crucial. Here, the photo-assisted degradation of methylene blue (MB) dye under visible light and UV was achieved by using RGO photocatalyst loaded with ZnCuFeO in three different loaded 10%, 20%, and 30% called MRGO 10, MRGO 20, and MRGO 30.
View Article and Find Full Text PDFNat Commun
January 2025
Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai, China.
Photocatalytic overall water splitting is a promising approach for a sustainable hydrogen provision using solar energy. For sufficient solar energy utilization, this reaction ought to be operated based on visible-light-active semiconductors, which is very challenging. In this work, an F-expedited nitridation strategy is applied to modify the wide-bandgap semiconductor SrTiO for visible-light-driven photocatalytic overall water splitting.
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