Chalcogenide glass fibers are promising photonic tools to develop Fiber Evanescent Wave Spectroscopy (FEWS) optical sensors working in the mid-infrared region. Numerous pioneering works have already been carried out showing their efficiency, especially for bio-medical applications. Nevertheless, this technology remains confined to academic studies at the laboratory scale because chalcogenide glass fibers are difficult to shape to produce reliable, sensitive and compact sensors. In this paper, a new method for designing and fabricating a compact and robust sensing head with a selenide glass fiber is described. Compact looped sensing heads with diameter equal to 2 mm were thus shaped. This represents an outstanding achievement considering the brittleness of such uncoated fibers. FEWS experiments were implemented using alcoholic solutions as target samples showing that the sensitivity is higher than with the routinely used classical fiber. It is also shown that the best compromise in term of sensitivity is to fabricate a sensing head including two full loops. From a mechanical point of view, the breaking loads of the loop shaped head are also much higher than with classical fiber. Finally, this achievement paves the way for the use of mid-infrared technology during in situ and even in vivo medical operations. Indeed, is is now possible to slide a chalcogenide glass fiber in the operating channel of a standard 2.8 mm diameter catheter.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4239893 | PMC |
http://dx.doi.org/10.3390/s141017905 | DOI Listing |
ChemistryOpen
December 2024
School of Chemistry and School of Materials, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EPPr)N}], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'PPrNH)] (E, E'=Se, Se; S, Se). These complexes were characterized and used as single-source precursors through Aerosol-Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm).
View Article and Find Full Text PDFMicromachines (Basel)
October 2024
Shenzhen Key Laboratory of High-Performance Nontraditional Manufacturing, College of Mechatronics and Control Engineering, Shenzhen University, Shenzhen 518060, China.
The application of As-Se chalcogenide glasses in high-power laser delivery is hindered by their low damage threshold due to their weak chemical bonds. To solve this, we introduced germanium elements into the As-Se glasses and optimized the composition to raise the glass transition temperature (T) and enhance the laser damage threshold (LDT). From the correlation among various parameters including T, LDT, and fiber loss, we concluded an optimized composition of GeAsSe/GeAsSe glass.
View Article and Find Full Text PDFA fiber combiner is a flexible optical component that can superimpose the power of multiple lasers to yield much higher output power than the available power from a single laser source. In this work, we report the design, fabrication, and characterization of a high-efficiency mid-infrared 3 × 1 chalcogenide glass fiber combiner. For the first time, the fiber combiner has been fabricated based on Ge-As-S glass, which has a significantly higher damage threshold than the conventionally used As-S glass.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!