Synthesis of the originally proposed 8-oxo-8H-acenaphtho[1,2-b]pyrrol-9-carbonitrile led to a structural revision, and the product has now been identified as unknown compound 1-oxo-1H-phenalene-2,3-dicarbonitrile. The structural assignment was corroborated by detailed NMR studies and unambiguously confirmed by X-ray diffraction. A mechanism is proposed to explain the formation of this original heterocyclic scaffold. In addition, some new chemical transformations involving this compound are presented.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jo5016932 | DOI Listing |
Publication Analysis
Top Keywords
1-oxo-1h-phenalene-23-dicarbonitrile heteroaromatic
4
heteroaromatic scaffold
4
scaffold revised
4
revised structure
4
structure mechanistic
4
mechanistic studies
4
studies synthesis
4
synthesis originally
4
originally proposed
4
proposed 8-oxo-8h-acenaphtho[12-b]pyrrol-9-carbonitrile
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!