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Chirally sensitive electron-induced molecular breakup and the Vester-Ulbricht hypothesis. | LitMetric

Chirally sensitive electron-induced molecular breakup and the Vester-Ulbricht hypothesis.

Phys Rev Lett

Jorgensen Hall, University of Nebraska, Lincoln, Nebraska 68588-0299, USA.

Published: September 2014

We have studied dissociative electron attachment in sub-eV collisions between longitudinally polarized electrons and chiral bromocamphor molecules. For a given target enantiomer, the dissociative Br anion production depends on the helicity of the incident electrons, with an asymmetry that depends on the electron energy and is of order 3×10^{-4}. The existence of chiral sensitivity in a well-defined molecular breakup reaction demonstrates the viability of the Vester-Ulbrict hypothesis, namely, that the longitudinal polarization of cosmic beta radiation was responsible for the origins of biological homochirality.

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http://dx.doi.org/10.1103/PhysRevLett.113.118103DOI Listing

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