The Pd(iv) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl2) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO2 yolk-shell nanocatalyst activated by PhICl2 showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 °C.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c4cc05112b | DOI Listing |
Publication Analysis
Top Keywords
hydroalkoxylation reactions
8
highly lewis-acidic
4
lewis-acidic pdiv
4
pdiv surface
4
surface pd@sio2
4
pd@sio2 nanocatalysts
4
nanocatalysts hydroalkoxylation
4
reactions pdiv
4
pdiv species
4
species critical
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!