Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.
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Synthesis of chlorosilicates.
Angew Chem Int Ed Engl
November 2014
Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615 Bielefeld (Germany).
Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.
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