The title compound, C14H28N2O5S, was synthesized by the reaction of 2-[(methyl-sulfan-yl)meth-yl]oxirane with di-tert-butyl oxalate in hydrazine hydrate. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds into supra-molecular chains propagating along the b-axis direction.
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http://dx.doi.org/10.1107/S1600536814015062 | DOI Listing |
Sci Rep
January 2025
Department of Nutritional Sciences, Auburn University, Auburn, AL, 36849, USA.
Oxidative stress (OS) refers to the disruption in the balance between free radical generation and antioxidant defenses, leading to potential tissue damage. Reactive oxygen species (ROS) can interact with biological components, triggering processes like protein oxidation, lipid peroxidation, or DNA damage, resulting in the generation of several volatile organic compounds (VOCs). Recently, VOCs provided new insight into cellular metabolism and can serve as potential biomarkers.
View Article and Find Full Text PDFInorg Chem
January 2025
International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China.
Hg is highly toxic and can cause serious harm to the environment and humans. Thus, it is vital to develop efficient Hg sensors. In this work, a LMOF-based (LMOF = luminescent metal-organic framework) "turn-on" Hg sensor () is first developed by an aggregation-induced emission (AIE) functional ligand.
View Article and Find Full Text PDFPlants (Basel)
December 2024
Department of Plant Biology, Ecology and Earth Sciences, Faculty of Science, University of Extremadura, 06006 Badajoz, Spain.
The evaluation of the wide variety of allelochemicals present in allelopathic plants allows the detection of safer bioherbicides with new mechanisms of action. This study tested two phenolic compounds of essential oil (2-Methoxyphenol and 2,6-Di--butyl-4-methylphenol), which are commercially available. At 0.
View Article and Find Full Text PDFChem Asian J
January 2025
College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou, Fujian, 350002, PR China.
Organic light-emitting diodes (OLEDs) has been attracting much extensive interest owing to their advantages of high-definition and flexible displays. Many advances have been focused on boosting the efficiency and stability. Two innovative dimethylacridine-based emitters, 1,1,2,2-tetrakis(4- (2,7-di-tert-butyl-9,9-dimethylacridin-10(9H)-yl)phenyl ethene (AcTPE), and bis(4-(2,7-di-tert-butyl-9,9-dimethylacridin-10(9H)-yl)phenyl)methanone (Ac2BP) were designed and synthesized, in which TPE-baesed AcTPE presents AIE properties, and with the phenyl as spacer between the DMAC and carbony, aryl-ketone-based Ac2BP doesn't show AIE properties due to the absence of restriction of intramolecular rotations.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry, University of Melbourne, Parkville 3010, Victoria, Australia.
A search for switchable molecules has afforded a family of cobalt complexes featuring derivatives of 2-aminophenol: 4,6-di--butyl aminophenol (HL) and 2-anilino-4,6-di--butyl aminophenol (HL). The heteroleptic cobalt complexes incorporate a Metpa ligand (tpa = tris(2-pyridylmethyl)amine; = 0-3), which involves the methylation of the 6-position of the pyridine ring). Eight members of this family have been synthesized and characterized: [Co(HL)(tpa)](BPh) (), [Co(HL)(Metpa)](BPh) (), [Co(L)(Metpa)](BPh) (), [Co(HL)(Metpa)](BPh) (), [Co(L)(Metpa)](BPh) (), [Co(HL)(tpa)] (BPh)(ClO) (), [Co(L)(tpa)](BPh)(ClO) () and [Co(HL)(Metpa)](BPh) (), where the aminophenol-derived ligands are monoanionic in either the open shell radical iminosemiquinonate (L) or the closed shell protonated aminophenolate (HL).
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