This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita-Baylis-Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168899 | PMC |
| http://dx.doi.org/10.3762/bjoc.10.218 | DOI Listing |
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