Photoelectrochemical reduction of aqueous protons with a CuO|CuBi2O4 heterojunction under visible light irradiation.

Phys Chem Chem Phys

Christian Doppler Laboratory for Sustainable SynGas Chemistry, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.

Published: November 2014

AI Article Synopsis

Article Abstract

A p-type heterojunction photoelectrode consisting of platinized CuBi2O4 layered on a CuO film was prepared. The CuO|CuBi2O4|Pt electrode photo-generates H2 in pH neutral aqueous solution during visible light irradiation and exhibits a substantially enhanced photocurrent compared to CuO|Pt and CuBi2O4|Pt electrodes. Reduced electron-hole recombination by the band offsets in the heterostructure is responsible for the improved photoelectrochemical performance of CuO|CuBi2O4 with a small band-gap of approximately 1.5 eV.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c4cp03883eDOI Listing

Publication Analysis

Top Keywords

visible light
8
light irradiation
8
photoelectrochemical reduction
4
reduction aqueous
4
aqueous protons
4
protons cuo|cubi2o4
4
cuo|cubi2o4 heterojunction
4
heterojunction visible
4
irradiation p-type
4
p-type heterojunction
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!