The synthesis of a rigid, planar H-type anthracene derivative is described. Single-crystalline ribbons at micro- and nanometer sizes can be controllably produced and transistors based on an individual ribbon can be fabricated in situ through a newly developed "organic ribbon mask" method, in which the channel length of the transistors can be easily scaled down to sub-micrometer level.
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http://dx.doi.org/10.1002/adma.200800341 | DOI Listing |
Small
December 2024
Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE, 68588, USA.
Science
June 2024
State Key Laboratory for Mesoscopic Physics, Frontiers Science Center for Nano-optoelectronics, Academy for Advanced Interdisciplinary Studies, School of Physics, Peking University, Beijing, China.
J Am Chem Soc
February 2023
Center for Advancing Electronics Dresden (cfaed), Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, Dresden01062, Germany.
Electrically conductive coordination polymers and metal-organic frameworks are attractive emerging electroactive materials for (opto-)electronics. However, developing semiconducting coordination polymers with high charge carrier mobility for devices remains a major challenge, urgently requiring the rational design of ligands and topological networks with desired electronic structures. Herein, we demonstrate a strategy for synthesizing high-mobility semiconducting conjugated coordination polymers (c-CPs) utilizing novel conjugated ligands with symmetry, namely, "4 + 2" phenyl ligands.
View Article and Find Full Text PDFNanoscale
April 2022
Department of Electrical and Computer Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588, USA.
Among group IV monochalcogenides, layered GeSe is of interest for its anisotropic properties, 1.3 eV direct band gap, ferroelectricity, high mobility, and excellent environmental stability. Electronic, optoelectronic and photovoltaic applications depend on the development of synthesis approaches that yield large quantities of crystalline flakes with controllable size and thickness.
View Article and Find Full Text PDFAcc Chem Res
December 2021
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China.
ConspectusSingle crystals of organic semiconductors (OSCs) are believed to have both high mobility and intrinsic flexibility, making them promising candidates for flexible electronic/optoelectronic applications and being consistently pursued by researchers. The van der Waals force in OSC enables low-temperature solution processing of single crystals, but the relatively weak binding energy brings challenges in forming large, uniform, and defect-free single crystals. To promote the study on OSC single crystals, a generalized method that grows high-quality crystals in an easy-to-handle, time/resource-saving, and repeatable manner is apparently necessary.
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