Presented in the present paper is a compact instrument developed for rapid, sensitive and continuous monitoring of trace gases in air, with results shown for carbon monoxide concentration. This instrument takes advantage of recent technology in mid-infrared quantum cascaded laser (QCL) operating at 4.8 microm and mercury cadmium telluride (HgCdTe) mid-infrared (MIR) detector, combing MIR multipass herriott cell with 76 m absorption path length to obtain low detection sensitivity down to 50 nmol x mol(-1) level in 4 s acquisition time. Meanwhile, in order to eliminate the instability induced by electrically modulated light source and effectively improve detection limit of the instrument, an optical structure with dual channel path was designed which is based on differential optical absorption spectroscopy method. The experimental results show that the instrument integrated with gas concentration inversion algorithm can be applied to in-situ measurements of trace gases without calibration. Additionally, operator could substitute a QCL operating at a different wavelength to measure other gases.
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Food Chem
December 2024
School of Chemical Sciences, The University of Auckland, 23 Symonds St., Auckland 1142, New Zealand; Te Pūnaha Matatini, Auckland, 1142, New Zealand. Electronic address:
Chemometrics; use of statistical models to characterise and understand complex chemical systems/samples, is an advancing field. In the dairy industry, the accurate prediction of milk composition involves combining mid-infrared spectroscopy with chemometric techniques for the evaluation of major constituents of milk. The increased interest in determination of detailed composition of dairy products, alongside emerging and more-widespread use of chemometric methodologies, have generated continuous improvement in predictive models for this application.
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December 2024
Department of Electrical and Computer Engineering, Boston University, Boston, MA 02215, USA.
Most molecules and dielectric materials have characteristic bond vibrations or phonon modes in the mid-infrared regime. However, infrared absorption spectroscopy lacks the sensitivity for detecting trace analytes due to the low quantum efficiency of infrared sensors. Here, we report mid-infrared photothermal plasmonic scattering (MIP-PS) spectroscopy to push the infrared detection limit toward nearly a hundred molecules in a plasmonic nanocavity.
View Article and Find Full Text PDFAnalyst
December 2024
Mechanobiology Institute (MBI), National University of Singapore, 5A Engineering Drive 1, 117411, Republic of Singapore.
Infrared spectro-microscopy is a powerful technique for analysing chemical maps of cells and tissues for biomedical and clinical applications, yet the strong water absorption in the mid-infrared region is a challenge to overcome, as it overlaps with the spectral fingerprints of biological components. Microfluidic chips offer ultimate control over the water layer thickness and are increasingly used in infrared spectro-microscopy. However, the actual impact of the water layer thickness on the instrument's performance is often left to the experimentalist's intuition and the peculiarities of specific instruments.
View Article and Find Full Text PDFAppl Spectrosc
December 2024
Research Division of Environmental Analytics, Process Analytics and Sensors, Institute of Chemical Technologies and Analytics, TU Wien, Vienna, Austria.
Volatile organic compounds (VOCs) are an ever-growing hazard for health and environment due to their increased emissions and accumulation in the air. Quantum cascade laser-based infrared (QCL-IR) sensors hold significant promise for gas monitoring, thanks to their compact, rugged design, high laser intensity, and high molecule-specific detection capabilities within the mid-infrared spectrum's fingerprint region. In this work, tunable external cavity QCLs were complemented by an innovative germanium-on-silicon integrated optics waveguide sensing platform with integrated microlenses for efficient backside optical interfacing for the tunable laser spectrometer.
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December 2024
School of Materials Science and Engineering, Harbin Institute of Technology, Shenzhen 518055, China.
Van Hove singularity (vHs), the singularity point of density of states (DOS) in crystalline solids, is a research hotspot in emerging phenomena such as light-matter interaction, superconducting, and quantum anomalous Hall effect. Although the significance of vHs in photothermoelectric (PTE) effect has been recognized, its integral role in electron excitation and thermoelectric effect is still unclear, particularly in the mid-infrared band that suffers from Pauli blockade in semimetals. Here, we unveil the Fermi-level-modulated PTE behavior in the vicinity of vHs in carbon nanotubes, employing ionic-liquid gating.
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