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Total synthesis of russuphelol: a case of mistaken chirality. | LitMetric

Total synthesis of russuphelol: a case of mistaken chirality.

Org Lett

Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States.

Published: September 2014

The chlorohydroquinone tetramer, russuphelol, does not have stereocenters; however, it was reported as a chiral optically active substance with stable enantiomeric conformations. The natural product is synthesized in six steps and 14% overall yield. Synthetic material was used to experimentally investigate its chiral properties.

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Source
http://dx.doi.org/10.1021/ol502459pDOI Listing

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