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Facilitating the Cope rearrangement by partial protonation: implications for synthesis and biosynthesis. | LitMetric
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Facilitating the Cope rearrangement by partial protonation: implications for synthesis and biosynthesis.

Phillip P Painter Bonnie M Wong Dean J Tantillo

Org Lett

Department of Chemistry, University of California-Davis, 1 Shields Avenue, Davis, California 95616, United States.

Published: September 2014

The theoretical investigation of concerted and stepwise Cope rearrangements of natural products led to the prediction that some concerted Cope rearrangements can be promoted by noncovalent association of their transition state structures with ammonium cations.

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 Source
http://dx.doi.org/10.1021/ol5023036DOI Listing

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