(N-phosphinoamidinate)cobalt-catalyzed hydroboration: alkene isomerization affords terminal selectivity.

Chemistry

Department of Chemistry, Dalhousie University, 6274 Coburg Road, P.O. Box 15000, Halifax, Nova Scotia B3H 4R2 (Canada).

Published: October 2014

Herein we establish the utility of a three-coordinate (N-phosphinoamidinate)cobalt(amido) pre-catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.

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Source
http://dx.doi.org/10.1002/chem.201403945DOI Listing

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