New well-defined, paramagnetic nickel complexes have been prepared and characterized by X-ray crystallography. The complexes were found to be active for the cross-coupling of alkyl electrophiles (especially ethyl 2-bromobutyrate) with alkyl Grignard reagents. The ligand architecture in these new complexes could potentially be rendered chiral, opening up future possibilities for performing asymmetric cross-coupling reactions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271139 | PMC |
| http://dx.doi.org/10.3390/molecules190913603 | DOI Listing |
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