A novel mesoporous "shell-in-shell" structured nanocatalyst (@Pd/meso-TiO2/Pd@meso-SiO2) with large surface area, enhanced synergy, and improved catalytic performance is created for catalyzing Suzuki-Miyaura coupling and 4-nitrophenol reduction reactions.
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A mesoporous "shell-in-shell" structured nanocatalyst with large surface area, enhanced synergy, and improved catalytic performance for Suzuki-Miyaura coupling reaction.
Chem Commun (Camb)
October 2014
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China.
A novel mesoporous "shell-in-shell" structured nanocatalyst (@Pd/meso-TiO2/Pd@meso-SiO2) with large surface area, enhanced synergy, and improved catalytic performance is created for catalyzing Suzuki-Miyaura coupling and 4-nitrophenol reduction reactions.
View Article and Find Full Text PDFHollow MnCo2O4 submicrospheres with multilevel interiors: from mesoporous spheres to yolk-in-double-shell structures.
ACS Appl Mater Interfaces
January 2014
Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, NSW 2522, Australia.
We present a general strategy to synthesize uniform MnCo2O4 submicrospheres with various hollow structures. By using MnCo-glycolate submicrospheres as the precursor with proper manipulation of ramping rates during the heating process, we have fabricated hollow MnCo2O4 submicrospheres with multilevel interiors, including mesoporous spheres, hollow spheres, yolk-shell spheres, shell-in-shell spheres, and yolk-in-double-shell spheres. Interestingly, when tested as anode materials in lithium ion batteries, the MnCo2O4 submicrospheres with a yolk-shell structure showed the best performance among these multilevel interior structures because these structures can not only supply a high contact area but also maintain a stable structure.
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