Purpose: The purpose of this study was to investigate the impact of different surface treatment methods and thermal ageing on the bond strength of autopolymerizing acrylic resin to Co-Cr.
Materials And Methods: Co-Cr alloy specimens were divided into five groups according to the surface conditioning methods. C: No treatment; SP: flamed with the Silano-Pen device; K: airborne particle abrasion with Al2O3; Co: airborne particle abrasion with silica-coated Al2O3; KSP: flamed with the Silano-Pen device after the group K experimental protocol. Then, autopolymerized acrylic resin was applied to the treated specimen surfaces. All the groups were divided into two subgroups with the thermal cycle and water storage to determine the durability of the bond. The bond strength test was applied in an universal test machine and treated Co-Cr alloys were analyzed by scanning electron microscope (SEM). Two-way analysis of variance (ANOVA) was used to determine the significant differences among surface treatments and thermocycling. Their interactons were followed by a multiple comparison' test performed uing a post hoc Tukey HSD test (α=.05).
Results: Surface treatments significantly increased repair strengths of repair resin to Co-Cr alloy. The repair strengths of Group K, and Co significantly decreased after 6,000 cycles (P<.001).
Conclusion: Thermocycling lead to a significant decrease in shear bond strength for air abrasion with silica-coated aluminum oxide particles. On the contrary, flaming with Silano-Pen did not cause a significant reduction in adhesion after thermocycling.
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http://dx.doi.org/10.4047/jap.2014.6.4.272 | DOI Listing |
Nano Lett
January 2025
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China.
Pnictogen bond (PnB) occurring on the group-15 elements is recognized as σ- or π-hole-based interaction that has garnered attention in the fields of anion recognition and organocatalysis. Due to the polyvalent feature of pnictogens and high directionality, PnB possesses potential in the design of convergent coassembled materials with acceptors containing lone pair electrons or anions, which however is rarely explored so far. Herein, we unveil the role of antimony (Sb)-based PnB donors in producing self-assembled chiroptical materials with lone pair electron containing acceptors.
View Article and Find Full Text PDFArch Pharm (Weinheim)
January 2025
Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child Health (NEUROFARBA), University of Florence, Sesto Fiorentino, Firenze, Italy.
2,2'-Thio-bis(4,6-dichlorophenol), namely bithionol, is a small molecule endowed with a multifaceted bioactivity. Its peculiar polychlorinated phenolic structure makes it a suitable candidate to explore its potentialities in establishing interaction patterns with enzymes of MedChem interest, such as the human carbonic anhydrase (hCA) metalloenzymes. Herein, bithionol was tested on a panel of specific hCAs through the stopped-flow technique, showing a promising micromolar inhibitory activity for the hCA II isoform.
View Article and Find Full Text PDFNat Commun
January 2025
Laboratoire Sciences et Ingénierie de la Matiére Molle, ESPCI Paris, CNRS, PSL University, Paris, France.
Stretchable elastic materials with high strength, toughness, and good ionic conductivity are highly desirable for wearable devices and stretchable batteries. Unfortunately, limited success has been reported to attain all of these properties simultaneously. Here, we report a family of ionically conductive elastomers (ICEs) without compromise between mechanical properties (high stiffness, reversible elasticity, fracture resistance) and ionic conductivity, by introducing a multiple network elastomer (MNE) architecture into a low polymer.
View Article and Find Full Text PDFEur J Oral Sci
January 2025
Department of Basic Sciences, Biomedical Stomatology Research Group, Faculty of Dentistry, Universidad de Antioquia U de A, Medellín, Colombia.
J Vis Exp
December 2024
School of Engineering and Materials Science, Queen Mary University of London.
Under current minimally invasive treatment regimes, minor tooth preparation and thinner biomimetic ceramic restoration are used to preserve the restored tooth's vitality, aesthetics, and function. New computer-aided design and computer-aided manufacturing (CAD/CAM) ceramic-like material are now available. To guarantee longevity, a dental clinician must know these newly launched product's mechanical strength compared to the relatively brittle glass-matrix ceramic.
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