A new selectophore for gadolinium selective sensor.

Based on a selective complexation of N'-(2-oxo-1,2-di(pyridin-2-yl)ethylidene)furan-2-carbohydrazide (L) with Gd(III) ions, it was used as a selectophore in construction of a Gd(III) selective PVC membrane sensor. Different compositions for the membrane were tested. The o-nitrophenyloctyl ether (NPOE) was used as suitable plasticizer, and a mixture of sodium tetraphenyl borate (NaTPB) and oleic acid (OA) as anion excluders. The proposed sensor displayed a Nernstian behavior with the slope of 19.9 ± 0.6 mV decade(-1) in concentration range of 1.0 × 10(-6) to 1.0 × 10(-2)mol L(-1). Detection limit was 4.2 × 10(-7)molL(-1) and response time was ~10s. Applicable pH range of the electrode was 4.2-8.0. Lifetime of the sensor is at least 10 weeks. Analysis of certified reference materials confirmed the accuracy of the proposed electrode.