Apparent fracture in polymeric fluids under step shear.

Phys Rev Lett

Soft Matter Physics Group, School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, United Kingdom.

Published: May 2013

Recent step strain experiments in well-entangled polymeric liquids demonstrated a bulk fracturelike phenomenon. We study this instability by using a modern version of the Doi-Edwards theory for entangled polymers, and we find close quantitative agreement with the experiments. The phenomenon occurs because the viscoelastic liquid is sheared into a rubbery state that possesses an elastic constitutive instability [G. Marrucci and N. Grizzuti, J. Rheol. 27, 433 (1983)]. The fracture is a transient manifestation of this instability, which relies on the amplification of spatially inhomogeneous fluctuations. This mechanism differs from the fracture in glassy materials and dense suspensions.

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http://dx.doi.org/10.1103/PhysRevLett.110.204503DOI Listing

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