A novel ring contraction/rearrangement sequence leading to functionalized 2,8-oxymethano-bridged di- and triquinane compounds is observed in the reaction of various substituted 1-methyl-4-isopropenyl-6-oxabicylo[3.2.1]octan-8-ones with Lewis acids. The reaction is novel and is unprecedented for the synthesis of di- and triquinane frameworks.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201407680 | DOI Listing |
Publication Analysis
Top Keywords
di- triquinane
8
unusual ring-contraction/rearrangement
4
ring-contraction/rearrangement sequence
4
sequence making
4
making functionalized
4
functionalized di-
4
di- triquinanes
4
triquinanes novel
4
novel ring
4
ring contraction/rearrangement
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!