Here we report on the synthesis of caesium doped graphene oxide (GO-Cs) and its application to the development of a novel NO2 gas sensor. The GO, synthesized by oxidation of graphite through chemical treatment, was doped with Cs by thermal solid-state reaction. The samples, dispersed in DI water by sonication, have been drop-casted on standard interdigitated Pt electrodes. The response of both pristine and Cs doped GO to NO2 at room temperature is studied by varying the gas concentration. The developed GO-Cs sensor shows a higher response to NO2 than the pristine GO based sensor due to the oxygen functional groups. The detection limit measured with GO-Cs sensor is ≈90 ppb.
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http://dx.doi.org/10.3762/bjnano.5.120 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Instytut Chemii Organicznej PAN: Instytut Chemii Organicznej Polskiej Akademii Nauk, Institute of Organic Chemistry, Kasprzaka 44/52, 01-224, Warsaw, POLAND.
The development of straightforward synthetic methods for photoactive polycyclic aromatic hydrocarbons (PAHs) that avoid Pd-catalyzed or radical-based processes remains a challenge. Such methods are essential to reducing the cost and environmental impact of organic photodevices. In this work, we present a one-pot synthetic approach for creating novel bipolar PAHs with extended π-conjugation, which are not accessible via conventional Pd-catalyzed routes.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, PR China; Science Island Branch of Graduate School, University of Science and Technology of China, Hefei 230026, PR China. Electronic address:
Recently, hybrid capacitive deionization (HCDI) has garnered significant attention for its potential in the selective extraction of cesium (Cs) from radioactive wastewater and salt lakes, which is crucial for resolving the supply-demand imbalance of cesium resources and eliminating radioactive contamination. However, developing HCDI electrodes capable of effectively separating and extracting Cs remains a significant challenge. In this work, we proposed an innovative strategy involving the doping of inactive metal ions to develop zinc-doped manganese hexacyanoferrate (ZMFC) as an HCDI cathode.
View Article and Find Full Text PDFInorg Chem
December 2024
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China.
Small
December 2024
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
Electroreduction of CO to CO by solid oxide electrolysis cells (SOEC) is an effective means to realize carbon neutralization. However, the sluggish kinetics at SOEC fuel electrode impedes its further practical application. Herein, the doping strategy of cesium ion (Cs) is employed to develop a series of perovskite-type fuel electrode materials, i.
View Article and Find Full Text PDFChemSusChem
December 2024
Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.
The double-perovskite material CsTiBr shows excellent photovoltaic potential, making it a promising alternative to lead-based materials. However, its high susceptibility to degradation in air has raised concerns about its practical application. This study introduces an interesting synthesis approach that significantly enhances the stability of CsTiBr powder.
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