(4R)-3-Hy-droxy-7-isopropyl-4-methyl-5,6-di-hydro-benzo-furan-2(4H)-one.

Acta Crystallogr Sect E Struct Rep Online

Departamento de Química, Universidad Simón Bolívar, Apartado 89000, Caracas 1020-A, Venezuela.

Published: July 2014

In the title compound, alternatively called α-hy-droxy-γ-alkyl-idenebutenolide, C12H16O3, two independent mol-ecules (A and B) crystallize in the asymmetric unit in each of which the 5,6-di-hydro-benzo ring has an envelope conformation. The torsion angle along the butadiene chain in the γ-alkyl-idenebutenolide core is -177.9 (2)° for mol-ecule A and 179.9 (2)° for mol-ecule B. In the crystal, O-H⋯O hydrogen bonds between hy-droxyl and carbonyl groups of adjacent independent mol-ecules form dimers with R (2) 2(10) loops.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120547PMC
http://dx.doi.org/10.1107/S1600536814014524DOI Listing

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