In the title compound, C22H21N3O5, the β-lactam (azetidin-2-one) ring is nearly planar [maximum deviation = 0.010 (1) Å] and makes dihedral angles of 69.22 (5), 55.32 (5) and 89.42 (4)° with the least-squares planes formed by the four C atoms of the morpholine ring, which adopts a chair conformation, the benzene ring and the xanthene ring system, respectively. In the crystal, C-H⋯O hydrogen-bond contacts connect neighbouring mol-ecules into infinite zigzag chains running parallel to the b axis.
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http://dx.doi.org/10.1107/S1600536814013464 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
September 2024
Laboratory of Organic and Physical Chemistry, Applied Bioorganic Chemistry Team, Faculty of Sciences, Ibnou Zohr University, Agadir, Morocco.
The benzimidazole moiety in the title mol-ecule, CHNO, is almost planar and oriented nearly perpendicular to the triazole ring. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into a network structure. There are no π-π inter-actions present but two weak C-H⋯π(ring) inter-actions are observed.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
September 2024
Department of Chemistry, M.M.A.M.C (Tribhuvan University) Biratnagar, Nepal.
This study presents the synthesis, characterization and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromo-phen-yl)-1,2,3,4-tetra-hydro-quinolin-4-yl]pyrrolidin-2-one, CHBrNO. In the title compound, the pyrrolidine ring adopts a distorted envelope configuration. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O, C-H⋯O and C-H⋯Br hydrogen bonds, forming a three-dimensional network.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
June 2024
Department of Chemistry, M.M.A.M.C (Tribhuvan University) Biratnagar, Nepal.
In the title compound, CHBrFNO, the pyrrolidine ring adopts an envelope conformation. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O, C-H⋯O, C-H⋯F and C-H⋯Br hydrogen bonds, forming a three-dimensional network. In addition, C-H⋯π inter-actions connect mol-ecules into ribbons along the -axis direction, consolidating the mol-ecular packing.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
May 2024
Department of Chemistry, M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal.
In the title compound, CHBrFNO, the oxa-diazole ring is essentially planar with a maximum deviation of 0.003 (2) Å. In the crystal, mol-ecular pairs are connected by N-H⋯N hydrogen bonds, forming dimers with an (8) motif.
View Article and Find Full Text PDFActa Crystallogr E Crystallogr Commun
May 2024
Laboratory of Organic and Physical Chemistry, Applied Bioorganic Chemistry Team, Faculty of Sciences, Ibnou Zohr University, Agadir, Morocco.
The benzimidazole entity of the title mol-ecule, CHNO, is almost planar (r.m.s.
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