{4-Amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidato}di-methyl-tin(IV).

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Published: July 2014

In the title compound, [Sn(CH3)2(C18H13N3O2)], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 4-amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate(2-) ligand and two C atoms from methyl ligands in a distorted trigonal-bipyramidal geometry. The dihedral angle between the naphthalene ring system and the benzene ring is 19.2 (2)°. In the crystal, weak N-H⋯O hydrogen bonds link the mol-ecules into zigzag chains along [010].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120628PMC
http://dx.doi.org/10.1107/S1600536814014652DOI Listing

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{4-Amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidato}di-methyl-tin(IV).

Acta Crystallogr Sect E Struct Rep Online

July 2014

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

In the title compound, [Sn(CH3)2(C18H13N3O2)], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 4-amino-N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate(2-) ligand and two C atoms from methyl ligands in a distorted trigonal-bipyramidal geometry. The dihedral angle between the naphthalene ring system and the benzene ring is 19.2 (2)°.

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