Here we report the synthesis of storable N-phenylcarbamate palladacycles that showed robust reactivity in the cross-coupling reaction with an alkyne-encoded protein with a second-order rate constant approaching 19 770 ± 930 M(-1) s(-1).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160388PMC
http://dx.doi.org/10.1039/c4cc02969kDOI Listing

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