We develop a bulk silver tip for tip-enhanced Raman scattering (TERS) and obtain TERS spectra of epitaxial graphene on the carbon face of 4H-SiC(000-1) with a high signal-to-noise ratio. Thanks to the high quality of TERS spectra we firstly find that the G band in the TERS spectra exhibits position-by-position variations in both lower wavenumber shifts and spectral broadening. The analysis of the variations reveals that the shifts and broadenings have a linear correlation between each other, indicating that the variations are induced by the position dependent local stress on graphene based on a uniaxial strain model.
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http://dx.doi.org/10.1039/c4cp02078b | DOI Listing |
Nanophotonics
March 2024
Institute of Physical and Theoretical Chemistry, Eberhard Karls University of Tübingen, 72076 Tübingen, Germany.
J Phys Chem Lett
October 2024
Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, MOE Key Laboratory of Computational Physical Sciences, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China.
The measurement of thermodynamic properties for nanosystems is essential to comprehend the inherent characteristics of nanomaterials. Traditional spectroscopy measurements, such as Raman or ultraviolet-visible spectroscopies, are limited to offering insights near the Γ point in the Brillouin zone and thus cannot precisely determine the system's thermodynamic properties, for example, heat capacity. Utilizing the intrinsic broad momentum distribution in highly confined plasmonic fields, here we take -hybridized carbyne as a proof-of-the-principle example to show that ultrahigh-resolution tip-enhanced Raman scattering (TERS) images have the ability to access all -points in the phonon Brillouin zone of one-dimensional nanosystems, allowing the comprehensive determination of vibrational features and heat capacity for finite carbon chains.
View Article and Find Full Text PDFJ Phys Chem Lett
October 2024
Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France.
Total-internal-reflection tip-enhanced Raman spectroscopy (TIR-TERS) imaging of amyloid-β (Aβ-L34T) fibrils is performed with nanoscale spatial resolution in water, using TERS tips fabricated by bipolar electrodeposition. Ideal experimental parameters are corroborated by both theoretical simulations and TIR-TERS measurements. TIR-TERS imaging reveals the predominant parallel β-sheet secondary structure of Aβ-L34T fibrils as well as the nanoscale spatial distribution of tyrosine, histidine, and phenylalanine aromatic amino acids.
View Article and Find Full Text PDFAnal Bioanal Chem
November 2024
Université de Franche-Comté, CNRS, Institut FEMTO-ST, 25000, Besançon, France.
Extracellular vesicles (EVs) have shown great potential as biomarkers since they reflect the physio-pathological status of the producing cell. In the context of cytotoxicity, it has been found that exposing cells to toxicants leads to changes in protein expression and the cargo of the EVs they produce. Here, we studied large extracellular vesicles (lEVs) derived from human microvascular endothelial cells (HMEC-1) to detect the modifications induced by cell exposure to benzo[a]pyrene (B[a]P).
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2024
Department of Physical Chemistry, Fritz-Haber Institute of the Max-Planck Society, Faradayweg 4-6, Berlin 14195, Germany.
Tip-enhanced Raman spectroscopy (TERS), combined with low-temperature scanning tunnelling microscopy (STM), has emerged as a highly sensitive method for chemical characterization, offering even sub-molecular resolution. However, its exceptional sensitivity is generally limited to molecules adsorbed onto plasmonic surfaces. Here we demonstrate single-molecule TERS for fullerene (C) adsorbed on the Si(111)-(7 × 7) reconstructed surface.
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