Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst.

Angew Chem Int Ed Engl

Max-Planck-Institut für Strahlenchemie, Stiftstrasse 34-36, D-45470 Mülheim an der Ruhr, Germany, Fax: (+49) 208-306-3952.

Published: August 2014

Primary alcohols such as ethanol or benzyl alcohol are selectively and catalytically oxidized by the mononuclear copper(II) radical complex 1-a functional model of the metalloenzyme galactose oxidase-with oxygen from air at 20°C to give the corresponding aldehydes and H2 O2 in about 60 % yield.

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http://dx.doi.org/10.1002/(SICI)1521-3773(19990419)38:8<1095::AID-ANIE1095>3.0.CO;2-IDOI Listing

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