Low-temperature reduction of brownmillerite CaFeO2.5 in LaAlO3/CaFeO2.5 heterostructures made on SrTiO3.

When LaAlO3/CaFeO2.5 thin-film heterostructures made on SrTiO3 were annealed with CaH2 at low temperatures below 300 °C, the brownmillerite CaFeO2.5 layer was reduced to CaFeO2 with an infinite-layer structure while both the LaAlO3 capping layer and the SrTiO3 substrate remained intact. The reduction behaviour strongly depends on the lattice matching of LaAlO3 to CaFeO2.5, suggesting that oxygen ions migrate through the coherently grown LaAlO3 layer of the heterostructure predominantly in the out-of-plane direction. The structural defects near the interface in the relaxed-structure LaAlO3 capping layer prevent the oxygen ions from migrating.