Glassy carbon paste electrode (GCPE) was modified with graphene platinum hybrid nanoparticle (Gr-Pt hybrid NP) and used as a transducer for label and indicator free electrochemical genosensor. 22 mer oligonucleotides representing Escherichia coli bacteria were used as a model case. As far as it is known, this study is the first study where Gr-Pt hybrid NP was incorporated into GCPE and used for genosensor transducer. The extent of hybridization was determined by using differential pulse voltammetric signals of guanin oxidation. After the optimization of experimental parameters, analytical characteristics were investigated. The linear range was found between 1.5×10(-7) and 2.25×10(-6) M with the equation of y=1.6566x-2.6161 and R(2) of 0.9959. RSD and LOD were calculated as 4.2% (n=6) and 1.12×10(-9) M respectively.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.talanta.2014.06.021 | DOI Listing |
Adv Sci (Weinh)
December 2023
School of Materials Science and Engineering, Georgia Institute of Technology, 771 Ferst Drive, Atlanta, GA, 30332, USA.
Over the past decades, the design of active catalysts has been the subject of intense research efforts. However, there has been significantly less deliberate emphasis on rationally designing a catalyst system with a prolonged stability. A major obstacle comes from the ambiguity behind how catalyst degrades.
View Article and Find Full Text PDFMikrochim Acta
January 2018
Key Laboratory of Interface Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, China.
An electrochemiluminescent (ECL) aptamer based assay is described for thrombin. It is based on the use of carbon dots (C-dots) placed on polydopamine nanospheres loaded with silver nanoparticles (PDANS@Ag) and with probe DNA (pDNA). The PDANS possess high specific surface and can load a large number of C-dots.
View Article and Find Full Text PDFTalanta
November 2014
Muğla Sıtkı Koçman University, Faculty of Science, Chemistry Department, 48000 Kötekli, Muğla Turkey. Electronic address:
Glassy carbon paste electrode (GCPE) was modified with graphene platinum hybrid nanoparticle (Gr-Pt hybrid NP) and used as a transducer for label and indicator free electrochemical genosensor. 22 mer oligonucleotides representing Escherichia coli bacteria were used as a model case. As far as it is known, this study is the first study where Gr-Pt hybrid NP was incorporated into GCPE and used for genosensor transducer.
View Article and Find Full Text PDFACS Nano
May 2013
Elettra-Sincrotrone Trieste SCpA, SS 14 Km 163.5, 34149 Trieste, Italy.
The charge transfer rates of a localized excited electron to graphene monolayers with variable substrate coupling have been investigated by the core hole clock method with adsorbed argon. Expressed as charge transfer times, we find strong variations between ~3 fs (on graphene "valleys" on Ru(0001)) to ~16 fs (quasi-free graphene on SiC, O/Ru(0001), or SiO2/Ru). The values for the "hills" on Gr/Ru and on Gr/Pt(111) are in between, with the ratio 1.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!