Pore length scales and pore surface relaxivities of rock cores with different lithologies were studied on a 2MHz Rock Core Analyzer. To determine the pore length scales of the rock cores, the high eigenmodes of spin bearing molecules satisfying the diffusion equation were detected with optimized encoding periods in the presence of internal magnetic fields Bin. The results were confirmed using a 64MHz NMR system, which supports the feasibility of high eigenmode detection at fields as low as 2MHz. Furthermore, this methodology was combined with relaxometry measurements to a two-dimensional experiment, which provides correlation between pore length and relaxation time. This techniques also yields information on the surface relaxivity of the rock cores. The estimated surface relaxivities were then compared to the results using an independent NMR method.
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http://dx.doi.org/10.1016/j.jmr.2014.07.005 | DOI Listing |
Adv Mater
January 2025
Macromolecular Engineering Laboratory, Department of Mechanical and Process Engineering, ETH Zurich, Zurich, 8092, Switzerland.
J Phys Chem B
January 2025
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States.
Artificial water channels (AWCs) have emerged as a promising framework for stable water permeation, with water transport rates comparable to aquaporins (3.4-40.3 × 10 HO/channel/s).
View Article and Find Full Text PDFLangmuir
December 2024
School of Mechanical and Mining Engineering, University of Queensland, Brisbane 4072, Australia.
Coalbed methane (CBM) reservoir modification based on chemical solvent treatment could change the coal microstructure, which further affects the adsorption capacity and flow characteristics of this clean energy. Coal samples were extracted by tetrahydrofuran (THF), carbon disulfide (CS), and hydrochloric acid (HCl). Low-pressure nitrogen adsorption, carbon dioxide adsorption, Fourier transform infrared spectroscopy, and methane isothermal adsorption test were adopted.
View Article and Find Full Text PDFWater Res
December 2024
Center for Environmental Solutions & Emergency Response, U.S. Environmental Protection Agency, Cincinnati, OH 45268, USA. Electronic address:
Single-solute batch kinetic and isotherm experiments were conducted in Type 1 (18.2 MΩ·cm resistivity) water supplemented with 10 mM carbonate buffer (pH 7.75, 25 °C) for nine drinking water relevant perfluoroalkyl chemicals and three bituminous-coal based granular activated carbons (GACs).
View Article and Find Full Text PDFThe mechanisms of soil preferential flow occurrence and development are influenced by topographic and geomorphological factors. However, the complex distribution patterns of soil preferential flow paths on different slopes remain unclear. Therefore, taking the subtropical evergreen broad-leaved forest area of Simian Mountain as the study area, this study conducted a quantitative analysis of the spatial distribution characteristics and spatial association of soil preferential flow at different slope positions (slope shoulder (SS), mid-slope (SM) and slope foot (SF)) using field staining tracer tests and spatial point pattern analysis.
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