Well-ordered polymer nano-fibers with self-cleaning property by disturbing crystallization process.

Nanoscale Res Lett

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People's Republic of China.

Published: August 2014

Bionic self-cleaning surfaces with well-ordered polymer nano-fibers are firstly fabricated by disturbing crystallization during one-step coating-curing process. Orderly thin (100 nm) and long (5-10 μm) polymer nano-fibers with a certain direction are fabricated by external macroscopic force (F blow) interference introduced by H2 gas flow, leading to superior superhydrophobicity with a water contact angle (WCA) of 170° and a water sliding angle (WSA) of 0-1°. In contrast, nano-wires and nano-bridges (1-8 μm in length/10-80 nm in width) are generated by "spinning/stretching" under internal microscopic force (F T) interference due to significant temperature difference in the non-uniform cooling medium. The findings provide a novel theoretical basis for controllable polymer "bionic lotus" surface and will further promote practical application in many engineering fields such as drag-reduction and anti-icing.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4106910PMC
http://dx.doi.org/10.1186/1556-276X-9-352DOI Listing

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