We have developed a simple model that is able to describe and predict hysteresis behavior inside Mumetal magnetic shields, when the shields are submitted to ultra-low frequency (<0.01 Hz) magnetic perturbations with amplitudes lower than 60 μT. This predictive model has been implemented in a software to perform an active compensation system. With this compensation the attenuation of longitudinal magnetic fields is increased by two orders of magnitude. The system is now integrated in the cold atom space clock called PHARAO. The clock will fly onboard the International Space Station in the frame of the ACES space mission.
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http://dx.doi.org/10.1063/1.4890561 | DOI Listing |
Sci Rep
January 2025
Laboratory of Functional and Molecular Imaging, National Institute of Neurological Disorders and Stroke, National Institutes of Health, Bethesda, MD, 20892, USA.
In a step towards generating switchable MRI cellular labels, we demonstrate in-situ field switching of micron scale metamagnetic Iron-Rhodium (FeRh) thin film particles. A thin-film (200 nm) FeRh sample was fabricated and patterned into an array of progressively smaller squares with sizes ranging from 500 μm down to 1 μm. The large first order phase change from antiferromagnetic to ferromagnetic state was characterized using vibrating sample magnetometry, magnetic force microscopy, and MRI.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
School of Chemical & Biomolecular Sciences, Southern Illinois University, Carbondale, Illinois 62901-6632, United States.
The antibiotic metronidazole (MNZ) has gained interest as a potential MRI contrast agent for imaging hypoxia. N-labeled MNZ can be efficiently hyperpolarized via SABRE-SHEATH (Signal Amplification By Reversible Exchange in SHield Enables Alignment Transfer to Heteronuclei), but the envisioned MRI approach requires that MNZ rapidly undergoes structural changes in hypoxic environments with significant N frequency differences manifested in its downstream metabolic products. We have performed NMR studies of the anticipated metabolic product amino-MNZ (despite anticipated stability concerns) accompanied by computational density functional theory (DFT) studies to predict the N chemical shifts of different relevant species.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, United States.
ConspectusUnderstanding f element-ligand covalency is at the center of efforts to design new separations schemes for spent nuclear fuel, and is therefore of signficant fundamental and practical importance. Considerable effort has been invested into quantifying covalency in f element-ligand bonding. Over the past decade, numerous studies have employed a variety of techniques to study covalency, including XANES, EPR, and optical spectroscopies, as well as X-ray crystallography.
View Article and Find Full Text PDFSmall
January 2025
NanoScience Technology Center, Department of Materials Science and Engineering, Department of Chemistry, Renewable Energy and Chemical Transformation Cluster, The Stephen W. Hawking Center for Microgravity Research and Education, University of Central Florida, Orlando, FL, 32826, USA.
Since the explosive growth of state-of-the-art electronics and devices raises concerns about electromagnetic pollution, exploring novel and efficient electromagnetic interference (EMI) shielding materials is desirable and crucial. TiCT MXenes hold significant EMI shielding potential due to their inherent characteristics, including lightweight, metal-like conductivities, unique layered structure, and facile processing. Nonetheless, it remains challenging to fabricate TiCT MXenes-based EMI shielding materials with efficient shielding capability and low reflection.
View Article and Find Full Text PDFSci Rep
January 2025
School of Electrical Engineering, University of Tehran, Tehran, 14179-35840, Iran.
This paper introduces an analytical method for studying power transmission through an infinite array of helical-shaped metal particles in a lossy dielectric medium. While the assessment of composite slabs' transmitted power has been extensively researched in the electromagnetic interference (EMI) shielding field, many studies lack an adequate problem description. The primary inadequacy of these studies is the need for an analytical framework.
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