Complex-formation-enhanced fluorescence quenching effect for efficient detection of picric acid.

Chemistry

Department of Chemistry, Key Laboratory of Functional Inorganic Materials of Anhui Province, Anhui University, Hefei 230039 (P.R. China), Fax: (+86) 551-63861279.

Published: September 2014

Amine-functionalized α-cyanostilbene derivatives (Z)-2-(4-aminophenyl)-3-(4-butoxyphenyl)acrylonitrile (ABA) and (Z)-3-(4-butoxyphenyl)-2-[4-(butylamino)phenyl]acrylonitrile (BBA) were designed for specific recognition of picric acid (PA), an environmental and biological pollutant. The 1:1 host-guest complexes formed between the chemosensors and PA enhanced fluorescence quenching, thus leading to sensitive and selective detection in aqueous media and the solid phase.

Download full-text PDF

Source
http://dx.doi.org/10.1002/chem.201402790DOI Listing

Publication Analysis

Top Keywords

fluorescence quenching
8
picric acid
8
complex-formation-enhanced fluorescence
4
quenching efficient
4
efficient detection
4
detection picric
4
acid amine-functionalized
4
amine-functionalized α-cyanostilbene
4
α-cyanostilbene derivatives
4
derivatives z-2-4-aminophenyl-3-4-butoxyphenylacrylonitrile
4

Similar Publications

Carbon dots (CDs), one type of zero-dimensional carbon nanomaterial, showed extensive application in food analysis. Herein, CDs as fluorometry and colorimetry probes were developed to determine peroxydisulfate (PDS) and phosphate ion (Pi) in food samples. CDs were developed with one-pot hydrothermal process from 5-amino salicylic acid and o/m-phenylenediamine named o/m-CDs.

View Article and Find Full Text PDF

Intrinsic fluorescence hydrogels for ON/OFF screening of antidiabetic drugs: assessing α-glucosidase inhibition by acarbose.

J Mater Chem B

January 2025

Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, 13071 Ciudad Real, Spain.

Diabetes remains one of the most prevalent chronic diseases globally, significantly impacting mortality ratetables. The development of effective treatments for controlling glucose level in blood is critical to improve the quality of life of patients with diabetes. In this sense, smart optical sensors using hydrogels, responsive to external stimuli, have emerged as a revolutionary approach to diabetes care.

View Article and Find Full Text PDF

Gold-silver synergism has been well documented in many scientific works dealing with luminescent nanostructures that are exploitable in biomedical and environmental application. Frequently, the ratio of Au : Ag in synthetic mixtures was varied to influence the extent of Au-Ag synergism of the resulting luminescent gold-silver nanoclusters (GSNCs). However, in our approach, a new step, maturing under differing conditions using the same Au : Ag ratio (5 : 1), has been investigated systematically for the very first time.

View Article and Find Full Text PDF

(, Hi) is an opportunistic bacterium that colonizes the upper respiratory tract of humans and frequently causes meningitis, pneumonia, sepsis, and other severe infections in children. Early and accurate detection of is essential for effective diagnosis and treatment. In this study, we established a novel diagnostic method by integrating the CRISPR-Cas12a detection platform with multiple cross-displacement amplification (MCDA), termed the Hi-MCDA-CRISPR assay.

View Article and Find Full Text PDF

The fused heterocycle 1-(imidazo[5,1-a]isoquinolin-3-yl)naphthalen-2-ol (LH) has been synthesized and characterized by spectroscopic methods. Probe LH upon irradiation with λ = 336 nm exhibited strong fluorescence with λ = 437 nm in MeOH/HEPES buffer (5 mM, pH = 7.4, 2:8, v/v).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!