Scanning tunnelling microscopy (STM) studies have found stripe-like domains on gold nanoparticles (NPs) coated with certain binary mixtures of ligand molecules. The majority of these NPs' properties have been investigated for particles in solvents. Yet, most STM studies are for NPs in a dry state. Images of the same particles in air and liquid have not been obtained yet. In this work, a judicious choice of ligand molecules led to NPs with close-to-ideal STM imaging conditions in air and in 1-phenyloctane (PO). Large datasets under both conditions were acquired and rapidly evaluated through power spectral density (PSD) analysis. The result is a quantitative comparison of stripe-like domains in air and PO on the same NPs. PSD analysis determines a characteristic length-scale for these domains of ~1.0 nm in air and in PO showing persistence of striped domains in these two media. A length scale of ~0.7 nm for homoligand NPs was found.
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Angew Chem Int Ed Engl
January 2025
Max Planck-EPFL Laboratory for Molecular Nanoscience, Institut de Physique de la Matière Condensée, École Polytechnique Fédérale de Lausanne, CH 1015 Lausanne, Switzerland, 1005, Lausanne, SWITZERLAND.
Efficient catalytic water splitting demands advanced catalysts to improve the slow kinetics of the oxygen evolution reaction (OER). Earth-abundant transition metal oxides show promising OER activity in alkaline media. However, most experimental information available is either from post-mortem studies or in-situ space-averaged X-ray techniques in the micrometer range.
View Article and Find Full Text PDFSci Transl Med
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Institute for Stroke and Dementia Research (ISD), University Hospital, LMU Munich, 81377 Munich, Germany.
In Alzheimer's disease (AD), amyloid-β (Aβ) triggers the aggregation and spreading of tau pathology, which drives neurodegeneration and cognitive decline. However, the pathophysiological link between Aβ and tau remains unclear, which hinders therapeutic efforts to attenuate Aβ-related tau accumulation. Aβ has been found to trigger neuronal hyperactivity and hyperconnectivity, and preclinical research has shown that tau spreads across connected neurons in an activity-dependent manner.
View Article and Find Full Text PDFAvian Pathol
January 2025
São Paulo State University (UNESP), School of Agricultural and Veterinary Sciences, Jaboticabal, SP, 14884-900, Brazil.
It was previously reported that utilization of tetrathionate and 1,2-propanediol by spp. through the metabolic pathways encoded by and operons are related to overgrowth and out-competing microbiota in an anaerobic environment. However, recent knowledge demonstrated which strains in the absence of and genes provoke both higher intestinal colonization and spreading bacteria on faeces in relation to their respective wild-type strain, and generate more prominent inflammation as well.
View Article and Find Full Text PDFFront Psychol
January 2025
Psychoeducation School, University of Montreal, Montreal, QC, Canada.
Introduction: As people age, chronic stress, resulting in prolonged or repeated activation of the hypothalamic-pituitary-adrenal (HPA) axis, has been associated with long-term adverse health outcomes. Coping strategies and social support have been recognized as contributing to resilience to stress in older adults. Few studies have evaluated stress management training (SMT) interventions based on psychoneuroendocrinology that were designed to be delivered to healthy older adults in community settings.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Philipps-Universität Marburg, Fachbereich Chemie, Hans-Meerwein-Str. 4, 35032 Marburg, Germany.
Acenes are an important class of polycyclic aromatic hydrocarbons that have gained considerable attention from chemists, physicists, and material scientists, due to their exceptional potential for organic electronics. They serve as an ideal platform for studying the physical and chemical properties of sp carbon frameworks in the one-dimensional limit and also provide a fertile playground to explore magnetism in graphenic nanostructures due to their zigzag edge topology. While higher acenes up to tridecacene have been successfully generated by means of on-surface synthesis, it is imperative to extend their synthesis toward even longer homologues to comprehensively understand the evolution of their electronic ground state.
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