Synthesis and characterization of gold nanotube/nanowire-polyurethane composite based on castor oil and polyethylene glycol.

Mater Sci Eng C Mater Biol Appl

Materials Science and Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran. Electronic address:

Published: September 2014

AI Article Synopsis

  • Gold nanotubes/nanowires (GNT/NW) were synthesized using a template-assisted technique and mixed with a castor oil-polyethylene glycol based polyurethane (PU) to create porous scaffolds for biomedical use, testing two concentrations: 100 and 50 ppm.* -
  • The composite scaffolds were analyzed through various methods, including infrared spectroscopy and scanning electron microscopy, highlighting significant improvements in thermal and mechanical properties with the addition of GNT/NW, particularly at the 50 ppm concentration.* -
  • Enhanced cell attachment and proliferation were observed in the 50 ppm GNT/NW composites due to hydrogen bonding with the PU matrix, leading to better surface properties compared to pure PU.*

Article Abstract

Gold nanotubes/nanowires (GNT/NW) were synthesized by using the template-assisted electrodeposition technique and mixed with castor oil-polyethylene glycol based polyurethane (PU) to fabricate porous composite scaffolds for biomedical application. 100 and 50 ppm of GNT/NW were used to synthesize composites. The composite scaffolds were characterized by Fourier transform infrared spectroscopy, dynamic mechanical thermal analysis, differential scanning calorimetry, and scanning electron microscopy. Cell attachment on polyurethane-GNT/NW composites was investigated using fat-derived mesenchymal stem cells. Addition of 50 or 100 ppm GNT/NW had significant effects on thermal, mechanical, and cell attachment of polyurethane. Higher crosslink density and better cell attachment and proliferation were observed in polyurethane containing 50 ppm GNT/NW. The results revealed that GNT/NW formed hydrogen bonding with the polyurethane matrix and improved the thermomechanical properties of nanocomposites. Compared with pure PU, better cellular attachment on polyurethane-GNT/NW composites was observed resulting from the improved surface properties of composites.

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http://dx.doi.org/10.1016/j.msec.2014.05.030DOI Listing

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Article Synopsis
  • Gold nanotubes/nanowires (GNT/NW) were synthesized using a template-assisted technique and mixed with a castor oil-polyethylene glycol based polyurethane (PU) to create porous scaffolds for biomedical use, testing two concentrations: 100 and 50 ppm.* -
  • The composite scaffolds were analyzed through various methods, including infrared spectroscopy and scanning electron microscopy, highlighting significant improvements in thermal and mechanical properties with the addition of GNT/NW, particularly at the 50 ppm concentration.* -
  • Enhanced cell attachment and proliferation were observed in the 50 ppm GNT/NW composites due to hydrogen bonding with the PU matrix, leading to better surface properties compared to pure PU.*
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