Zero-field slow magnetic relaxation in a uranium(III) complex with a radical ligand.

Chem Commun (Camb)

Centro de Ciências e Tecnologias Nucleares (C2TN)/CFMCUL, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10 ao km 139,7, P-2695-066 Bobadela LRS, Portugal.

Published: September 2014

[U(Tp(Me2))2(bipy˙)], a uranium(III) complex with a radical bipyridine ligand which has magnetic properties with contributions from both the ligand and the metal, presents slow relaxation of the magnetisation at low temperatures, already under zero static magnetic field, and energy barriers slightly above the non-radical analogues.

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http://dx.doi.org/10.1039/c4cc04486jDOI Listing

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