The ring opening reaction of 1,3-dithiol-2-one systems is fully reversible.

Chem Commun (Camb)

Institut fur Biochemie, Ernst-Moritz-Arndt-Universitat Greifswald, Felix-Hausdorff-Strasse 4, 17487 Greifswald, Germany.

Published: September 2014

The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand acts as an efficient trap.

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Source
http://dx.doi.org/10.1039/c4cc04414bDOI Listing

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