Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium.

Chem Commun (Camb)

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China.

Published: September 2014

Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium have been developed. They display two well-separated redox couples at low potentials. Each of the three readily accessible oxidation states can be distinguished by the absorbance at three different wavelengths.

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Source
http://dx.doi.org/10.1039/c4cc04268aDOI Listing

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