Preparation and characterization agar-based nanocomposite film reinforced by nanocrystalline cellulose.

Int J Biol Macromol

Department of Wood and Paper Technology, Faculty of Natural Resource, Tarbiat Modares University, P.O. Box 46414-356, Noor, Iran.

Published: September 2014

AI Article Synopsis

  • Nanocrystalline cellulose (NCC) was derived from microcrystalline cellulose (MCC) using sulfuric acid hydrolysis, yielding particles primarily around 30 nm in size.
  • Different amounts of NCC (2.5%, 5%, and 10% by weight) were added to an agar film solution, which were then analyzed using various techniques to assess their morphology and properties.
  • The addition of NCC notably reduced water vapor permeability and solubility of the films, while enhancing tensile strength and Young's modulus, though it decreased the elongation percentage and reduced the films' swelling and transparency.

Article Abstract

Nanocrystalline cellulose (NCC) was prepared from microcrystalline cellulose (MCC) with particle size of 24.7 μm using sulfuric acid hydrolysis technique. The obtained NCC revealed size of 0-100 nm, which the major part of them was about 30 nm. Then different contents (2.5, 5 and 10 wt%) of these NCC incorporated in agar film solution and the morphology, structure, and properties of the nanocomposite films were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier transforms infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), mechanical, physical and optical testing. Results showed that the water vapor permeability (WVP) and water solubility (WS) of the agar-based nanocomposite films significantly (P<0.05) decreased about 13% and 21%, respectively, upon increasing the NCC content to 10%. Tensile strength (TS) and Young's modulus (YM) values of nanocomposite films significantly increased (P≤0.05) with addition of NCC, whereas the elongation percent (E%) decreased not significantly (P>0.05). In addition, swelling percentage, transparency and light transmission of the films were decreased by incorporating NCC into polymer matrix.

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http://dx.doi.org/10.1016/j.ijbiomac.2014.07.013DOI Listing

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