The photoluminescence (PL) arising from silicon carbide nanoparticles has so far been associated with the quantum confinement effect or to radiative transitions between electronically active surface states. In this work we show that cubic phase silicon carbide nanoparticles with diameters in the range 45-500 nm can host other point defects responsible for photoinduced intrabandgap PL. We demonstrate that these nanoparticles exhibit single photon emission at room temperature with record saturation count rates of 7 × 10(6) counts/s. The realization of nonclassical emission from SiC nanoparticles extends their potential use from fluorescence biomarker beads to optically active quantum elements for next generation quantum sensing and nanophotonics. The single photon emission is related to single isolated SiC defects that give rise to states within the bandgap.
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http://dx.doi.org/10.1021/nn502719y | DOI Listing |
Small Methods
December 2024
School of Material Science and Engineering, National Institute of Technology Calicut, NIT Campus, Kozhikode, Kerala, 673601, India.
The work describes a novel sensing and transportation feasibility of the well-established antifungal drug Flucytosine (5-FC) using a 2D Silicon carbide (SiC) and Germanium-doped Silicon carbide (Ge@SiC) nanosheet via PBE level of Density functional theory. The computational study revealed that the drug molecules adhere to SiC and Ge@SiC sheets, maintaining their structural properties through physisorption on SiC and chemisorption on Ge@SiC. The charge transfer process associated with the adsorption is observed by Lowdin charge analysis and both the SiC and Ge@SiC sheets are identified as a feasible oxidation-based nanosensor for the drug.
View Article and Find Full Text PDFWe demonstrate a hybrid integrated optical frequency comb amplifier composed of a silicon carbide microcomb and a lithium niobate waveguide amplifier, which generates a 10-dB on-chip gain for the C+L band microcombs under 1480-nm laser pumping and an 8-dB gain under 980-nm laser pumping. It will solve the problem of low output power of microcombs and can be applied in various scenarios such as optical communication, lidar, optical computing, astronomical detection, atomic clocks, and more.
View Article and Find Full Text PDFPLoS One
December 2024
Power Electronics Research Center, University of Galway, Galway, Ireland.
The bidirectional inverter connected to the grid is a crucial component of DC distribution systems, however its operation can have an impact on the systems' overall efficiency. The usual load profile of such systems in residential buildings is quite dynamic, with multiple periods of light load, especially when compared to high-demand sectors. This study examines and contrasts the impact of SiC and Si power MOSFETs on the best configuration of a 5 kW bidirectional H6 inverter specifically designed for residential use applications.
View Article and Find Full Text PDFSensors (Basel)
December 2024
Institute of Systems Engineering, China Academy of Engineering Physics, Mianyang 621900, China.
Sensors operating in extreme environments are currently a focal point of global research. Extreme environmental conditions, such as overload, vibration, corrosion, high pressure, high temperature, and radiation, can affect the performance of sensors to the point of failure. It is noteworthy that, compared to the resistance to overload and vibration achieved through structural design, the application of sensors under high-temperature and radiation extreme conditions poses a greater challenge.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Department of Physics and Chemistry Emilio Segrè, University of Palermo, Via Archirafi 36, 90123 Palermo, Italy.
Silicon carbide is a wide-bandgap semiconductor useful in a new class of power devices in the emerging area of high-temperature and high-voltage electronics. The diffusion of SiC devices is strictly related to the growth of high-quality substrates and epitaxial layers involving high-temperature treatment processing. In this work, we studied the thermal stability of substrates of 4H-SiC in an inert atmosphere in the range 1600-2000 °C.
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