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Selective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: a revised mechanism. | LitMetric
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Selective reduction of aromatic ketones in aqueous medium mediated by Ti(III)/Mn: a revised mechanism.

Antonio Rosales Juan Muñoz-Bascón Esther Roldan-Molina Mayra A Castañeda Natalia M Padial Andreas Gansäuer Ignacio Rodríguez-García J Enrique Oltra

J Org Chem

Departamento Química Orgánica, Facultad de Ciencias, Universidad de Granada , Campus Fuentenueva s/n, 18071 Granada, Spain.

Published: August 2014

An experimental study on the role played by each of the reagents involved in the selective reduction of aromatic ketones in aqueous medium is reported. In this reaction, the reduction of aromatic ketones is mediated by Cp2TiCl. Moreover, the presence of Mn in the reaction medium is mandatory. To account for these findings, a substantially revised mechanism is proposed.

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http://dx.doi.org/10.1021/jo501141yDOI Listing

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