The analytical utility of a micro-hollow cathode glow discharge plasma for detection of varied hydrocarbons was tested using acetone, ethanol, heptane, nitrobenzene, and toluene. Differences in fragmentation pathways, reflecting parent compound molecular structure, led to differences in optical emission patterns that can then potentially serve as signatures for the species of interest. Spectral simulations were performed emphasizing the CH (A(2)Δ-X(2)Π), CH (C(2)Σ-X(2)Π), and OH (A(2)Σ(+)-X(2)Π) electronic systems. The analytical utility of selected emission lines is demonstrated by a linear relationship between optical emission spectroscopy and parent compound concentration over a wide range, with detection limits extending down to parts per billion (ppb) levels.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1366/13-07160 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Determination of the carrier temperature in weakly confined semiconductor nanocrystals using time-resolved optical spectroscopy.
Nanoscale
January 2025
Physics and Chemistry of Nanostructures, Ghent University, 9000 Ghent, Belgium.
Many applications of nanocrystals rely on their use in light detection and emission. In recent years, nanocrystals with more relaxed carrier confinement, including so-called 'bulk' and 2D implementations, have made their stake. In such systems, the charge carriers generated after (photo-)excitation are spread over a semi-continuous density of states, behaviour controlled by the carrier temperature .
View Article and Find Full Text PDFTerahertz (THz) generation via photomixing on photoconductive antenna using twin delayed chirped pulses provides a long THz pulse with a narrow bandwidth. To generate a long pulse with a broad bandwidth, we propose a new, to the best of our knowledge, method that combines two long optical pulses with opposite chirps. The pulses exhibit temporal distributions of their instantaneous frequencies with opposite slopes.
View Article and Find Full Text PDFAchiral metasurfaces with near-field optical chirality have attracted great attention in molecular sensing and chiral emission control. Here, the circular dichroism (CD) response of an achiral metasurface induced by spatially selective coupling with polymethyl methacrylate (PMMA) molecules is demonstrated. A designed achiral metasurface with a V-shaped resonator exhibits large optical chirality with a strongly dissymmetric distribution under circular polarization.
View Article and Find Full Text PDFOn-chip spin-exchange relaxation-free (SERF) atomic magnetometers (AMs) require linearly polarized light as detection light whose wavelength is 795 nm. In this study, we propose and demonstrate an inverse-designed linearly polarized light emitter suitable for 795 nm wavelength light. Due to the fact that the electric field of the TE fundamental mode is almost a beam of linearly polarized light, we verified whether the emission light obtained when only coupling efficiency is taken as the objective function is linearly polarized.
View Article and Find Full Text PDFRemote epitaxial crystalline perovskites for ultrahigh-resolution micro-LED displays.
Nat Nanotechnol
January 2025
Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, China.
The miniaturization of light-emitting diodes (LEDs) is pivotal in ultrahigh-resolution displays. Metal-halide perovskites promise efficient light emission, long-range carrier transport and scalable manufacturing for bright microscale LED (micro-LED) displays. However, thin-film perovskites with inhomogeneous spatial distribution of light emission and unstable surface under lithography are incompatible with the micro-LED devices.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!