Calix[4]resorcinarene polyhydrazide (CPH) protected water dispersible fluorescent silver nanaoparticles (AgNps) were prepared by one-pot method using water soluble CPH and AgNO₃. (CPH) bearing hydrazide group on its periphery acts as a reducing agent and its web type of structure as a stabilizing agent for the formation of calix protected silver nanoparticles (CPH-AgNps). CPH-AgNps were found to be highly stable over 120 days at room temperature and at varied pH. CPH-AgNps were characterized by UV/Vis-spectroscopy, particle size analyzer (PSA), transmission electron microscopy (TEM) and Energy dispersive X-ray analysis (EDX). Duly characterized nanoparticles were explored for their application as sensitive and selective fluorescent chemosensors for various metal ions. It was found that nanoparticles were selective and sensitive only for Fe(3+) ions with the linear range of detection from 0.1 μM to 10 μM. CPH-AgNps were also found to exhibit good antimicrobial activity when compared with standard Chloramphenicol. The selectivity and antimicrobial activity of CPH-AgNps suggests its potential use as a sensor for Fe(III) ions in ecosystems prone to industrial pollution and as an antimicrobial agent in biological applications.
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http://dx.doi.org/10.1016/j.saa.2014.05.044 | DOI Listing |
Sci Rep
January 2025
College of Engineering, Applied Science University (ASU), Manama, Kingdom of Bahrain.
This paper presents an in-depth analytical investigation into the time-dependent flow of a Casson hybrid nanofluid over a radially stretching sheet. The study introduces the effects of magnetic fields and thermal radiation, along with velocity and thermal slip, to model real-world systems for enhancing heat transfer in critical industrial applications. The hybrid nanofluid consists of three nanoparticles-Copper and Graphene Oxide-suspended in Kerosene Oil, selected for their stable and superior thermal properties.
View Article and Find Full Text PDFAm J Clin Nutr
January 2025
Department of Human Biology, NUTRIM Institute of Nutrition and Translational Research in Metabolism, Maastricht University Medical Centre+, Maastricht, the Netherlands. Electronic address:
Background: Industrial processing and storage of milk products can strongly increase protein glycation level. Previously, we have reported that ingestion of highly glycated milk protein attenuates the post-prandial rise in plasma lysine concentrations when compared to the ingestion of an equivalent amount of milk protein with a low glycation level. Whether the attenuated increase in plasma lysine availability is attributed to compromised protein digestion and subsequent lysine absorption remains to be established.
View Article and Find Full Text PDFInjury
December 2024
Hull Royal Infirmary, Anlaby Road, Kingston upon Hull HU3 2JZ, UK. Electronic address:
Frame configuration for the management of complex tibial fractures is highly variable and is dependent upon both fracture pattern and surgeon preference. The optimal number of rings to use when designing a frame remains uncertain. Traditionally larger, multi-ring-per-segment constructs have been assumed to offer optimal stability and therefore favourable conditions for fracture healing but there is little in-vivo evidence for this and the recent concept of reverse dynamisation challenges this approach.
View Article and Find Full Text PDFJ Environ Manage
January 2025
State Key Laboratory of Heavy Oil Processing and Centre for Bioengineering and Biotechnology, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580, China. Electronic address:
Polycyclic aromatic hydrocarbons (PAHs) are persistent organic pollutants with mutagenicity, carcinogenicity and teratogenicity, widely distributed in the environment. Effective biodegradation of PAHs is highly required, especially in wastewater. An efficient PAHs degrading strain Streptomyces sp.
View Article and Find Full Text PDFKidney360
November 2024
The Departments of Medicine, Veterans Affairs Palo Alto Healthcare System and Stanford University, Palo Alto, CA, USA 94304.
Background: Hemodialysis may excessively remove valuable solutes. Untargeted metabolomics data from a prior study suggested that ergothioneine was depleted in the plasma of hemodialysis subjects. Ergothioneine is a dietary-derived solute with antioxidant properties.
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