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Surface functionalization of detonation nanodiamonds by phosphonic dichloride derivatives. | LitMetric

Surface functionalization of detonation nanodiamonds by phosphonic dichloride derivatives.

Langmuir

Institut Charles Gerhardt Montpellier, UMR 5253 CNRS/ENSCM/UM2/UM1, Université Montpellier 2, CC1701, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France.

Published: August 2014

AI Article Synopsis

Article Abstract

A new method for the functionalization of detonation nanodiamonds (DNDs) is proposed, on the basis of surface modification with phosphonic dichloride derivatives. DNDs were first modified by phenylphosphonic dichloride, and the grafting modes and hydrolytic stability under neutral conditions were investigated using (1)H, (13)C, and (31)P solid state NMR spectroscopy, Fourier transform infrared spectroscopy, as well as elemental analysis. Then, in order to illustrate the possibilities offered by this method, DNDs functionalized by mesityl imidazolium groups were obtained by postmodification of DNDs modified by 12-bromododecylphosphonic dichloride. The oxidative thermal stability of the functionalized DNDs was investigated using thermogravimetric analysis.

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Source
http://dx.doi.org/10.1021/la5017565DOI Listing

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