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Nonanebis(peroxoic acid): a stable peracid for oxidative bromination of aminoanthracene-9,10-dione. | LitMetric

Nonanebis(peroxoic acid): a stable peracid for oxidative bromination of aminoanthracene-9,10-dione.

Beilstein J Org Chem

Department of Dyestuff Technology, Institute of Chemical Technology, N. P. Marg, Matunga, Mumbai - 400019, India. Tel.: 91-22-33612708.

Published: July 2014

A new protocol for the oxidative bromination of aminoanthracene-9,10-dione, which is highly deactivated towards the electrophilic substitution is investigated. The peracid, nonanebis(peroxoic acid), possesses advantages such as better stability at room temperature, it is easy to prepare and non-shock sensitiv as compared to the conventional peracids. The present protocol has a broad scope for the bromination of various substituted and unsubstituted aminoanthracene-9,10-diones.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077418PMC
http://dx.doi.org/10.3762/bjoc.10.90DOI Listing

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