Platinum-promoted Ga/Al₂O₃ as highly active, selective, and stable catalyst for the dehydrogenation of propane.

Angew Chem Int Ed Engl

Inorganic Chemistry and Catalysis Group, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht (The Netherlands) http://www.anorg.chem.uu.nl.

Published: August 2014

A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt% Ga, and 0.25 wt% K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga(3+) species are the active species and where Pt functions as a promoter.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499260PMC
http://dx.doi.org/10.1002/anie.201404460DOI Listing

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