A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt% Ga, and 0.25 wt% K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga(3+) species are the active species and where Pt functions as a promoter.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499260 | PMC |
http://dx.doi.org/10.1002/anie.201404460 | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!